Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM: Guinness is good for SET-LRP
نویسندگان
چکیده
منابع مشابه
Copper-mediated controlled radical polymerization under biological conditions: SET-LRP in blood serum.
The polymerization of hydrophilic monomers is reported utilizing Cu(0)-mediated living radical polymerization, SET-LRP. Highly active Cu(0) is formed in situ as a result of rapid disproportionation of [Cu(I)(Me6-Tren)Br] in serum. Disproportionation and homogenous controlled radical polymerization (PDI 1.09-1.25) are performed for the first time in blood (sheep) serum.
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ژورنال
عنوان ژورنال: Polymer Chemistry
سال: 2014
ISSN: 1759-9954,1759-9962
DOI: 10.1039/c3py01075a